Note: This is just my opinion. What I classify as a best move is a move that pushed someone further in the game, whether it was flashy or not. This doesn't mean that these players are the greatest ever, though some are, but that the moves they made changed the game for them or for their allies in a major way. This is in preparation for All Stars. Also THERE WILL BE SPOILERS
Number 2
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Julian ( thesexiestdude990) convincing the final 4 to have tribal council immediately after the immunity challenge Season 1: Hollywood
Holy crap was this a move. So it's the final 4. The biggest threat left in the game is Julian, however he loses the immunity challenge. He understands that if people start talking to each other (mainly Jerry ( gerardom13) and Anastasia ( c_shizz96)) they would probably vote Julian out and he would get 4th. But Julian was able to convince everyone at the final 4 to have tribal since everyone was ready and Jerry ended up leaving 3-1. This doesn't seem like a major move but it changed the game, because Jerry probably could have beat Glen ( glen5544) in the final 2 had he made it there, and Julian knew Jerry wasn't taking him to the final 2. The only reason this isn't number one is because Julian didn't end up making finals, had he though it COULD have been number 1.