Note: This is just my opinion. What I classify as a best move is a move that pushed someone further in the game, whether it was flashy or not. This doesn't mean that these players are the greatest ever, though some are, but that the moves they made changed the game for them or for their allies in a major way. This is in preparation for All Stars. Also THERE WILL BE SPOILERS
Number 4
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Julian ( thesexiestdude990) making a deal with Danny ( dinosaurdan) at the double tribal council Season 1: Hollywood
So Julian is in a sticky situation. The double tribal council happens and Joey leaves. Julian knows that Danny is his biggest threat left in the game, and Danny knows that Julian is as well. So after Nicky ( notnicky333) wins immunity there isn't much for Julian to do. But Julian, though high af, decides to go and make a deal with Danny that they won't vote each other off here. That way, Danny is on his side and when it ends up going to rocks with Julian being safe, Danny is sent home because he stuck to his deal with Julian. The only reason it is this low is because it worked out perfectly with the help of lady luck. But it sure was a damn good move that kept Julian in another round and showed why he is one of the best.