This list is a personal opinion. Therefore, any songs that were big and are low, doesn't mean they aren't famous, it means I don't enjoy them as much. PYN Below if you want to be tagged.
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2000 Light Years From Home | Beggars Banquet | 1968
Well well well, hello Rolling Stones! Nice to meet you. This is the beginning of the Stones Greatness. This song is extremely psychadelic, and shows how they have improved. The background noise is awesome, and the guitar flows so well back into the vocals. This song takes it out of Jagger's hands, and puts it into Richard's. Drumming is amazing, and feels like a poor man's "Paint It Black".